Professors: Charles H. Clapp, Margaret E. Kastner, George S. Shields (Dean of the College of Arts and Sciences), Timothy G. Strein (Chair), Eric S. Tillman, Brian W. Williams
Associate Professors:Dee Ann Casteel, Karen J. Castle, Molly M. McGuire, David S. Rovnyak, Thomas T. Shawe, Robert A. Stockland Jr., James S. Swan
Assistant Professors: William D. Kerber, Michael R. Krout (visiting), Steven P. Romberger (visiting), Thomas L. Selby
The degree of master of science in chemistry is designed to ensure students a thorough foundation in their field and to prepare them to continue their graduate education elsewhere or to obtain attractive employment in industry, government, or education. Graduate-level courses are offered in analytical, biochemical, environmental, inorganicc, organic, and physical chemistry.
Courses and Requirements
The program normally requires two full years.
Graduate students must complete at least seven courses for graduate credit, including research and thesis and a graduate seminar, in which they are expected to participate each semester.
There is no uniform set of course requirements; the courses recommended to students depend on their backgrounds and interests.
Candidates for the master of science degree must satisfactorily pass a written examination in their area of specialization and must either pass a comprehensive examination or obtain a satisfactory passing grade in an approved graduate credit course in each of three additional areas. In all, the candidate must in some way show competence in at least three of the four traditional areas of analytical, inorganic, organic, or physical chemistry. Students must present and orally defend a master’s thesis summarizing the results of their research.
Graduate teaching assistantships are awarded to nearly all chemistry M.S. candidates to support graduate study. In addition, summer research stipends are normally available for focused laboratory research during the summer months.
Research in the well-equipped laboratories of the Rooke Chemistry Building is conducted in analytical, inorganic, organic, environmental, physical, and biochemistry.
Faculty Research Interests
Dee Ann Casteel, Ph.D., University of Illinois-Urbana. Associate Professor, Organic Chemistry. Organic synthesis, synthesis of peroxides, anti-malarial, anti-viral, anti-tumor agents, medicinal chemistry.
Karen J. Castle, Ph.D., Oregon State University. Associate Professor, Physical Chemistry. Laser spectroscopic studies of atmospheric cooling and heating processes.
Charles H. Clapp, Ph.D., Harvard University. Professor, Biochemistry. Enzyme mechanisms and enzyme inhibitors.
Margaret E. Kastner, Ph.D., University of Notre Dame. Professor, Inorganic Chemistry. X-ray crystallography; chemical education.
William D. Kerber, Ph.D., University of North Carolina. Assistant Professor, Inorganic Chemistry. Redox chemistry of iron in natural waters; speciation of Fe(III) complexes; photochemical oxidation of carboxylates and phenols by iron(III).
Molly M. McGuire, Ph.D., Wisconsin-Madison, Associate Professor. Environmental Chemistry. Environmentally important redox reactions at clay mineral surfaces.
David Rovnyak, Ph.D., M.I.T., Associate Professor. Biophysical Chemistry. Application of magnetic resonance techniques to the study of biological macromolecules.
Thomas L. Selby, Ph.D., The Ohio State University, Assistant Professor, Biochemistry. Structure-Function Studies of Signaling Proteins; X-ray crystallography, biophysical characterization, enzymology, computational methods, and combinatorial protein libraries.
Thomas T. Shawe, Ph.D., Emory University. Associate Professor, Organic Chemistry. Organic synthetic methodology: stereoselective reactions and alkaloid synthesis.
George C. Shields, Ph.D., Georgia Institute of Technology. Professor, Computational Chemistry. Computational chemistry and structural biochemistry.
Robert A. Stockland, Jr., Ph.D., University of Missouri. Associate Professor, Inorganic and Polymer Chemistry. Design and synthesis of transition metal complexes with useful catalytic properties. Use of transition metal complexes to control polymerization and to modify polymers.
Timothy G. Strein, Ph.D., Pennsylvania State University, Professor, Analytical Chemistry. Capillary electrophoresis of biological fluids, charge transfer reactions at ultrasmall electrodes, GC/MS of environmental samples.
James S. Swan, Ph.D., Pennsylvania State University. Associate Professor, Analytical Biochemistry. Affinity chromatography; conformational changes in proteins.
Eric S. Tillman, Ph.D., University of Southern California, Associate Professor, Organic Chemistry. Synthesis of functionalized polymers, development of new initiating systems, synthesis of polymers for electronic and photochemical applications.
Brian W. Williams, Ph.D., Cornell University. Associate Professor, Physical Chemistry. Synthesis and spectroscopic characterization of solvatochromic molecules; fluores
The M.A. degree program in chemistry is for high school teachers of chemistry. It is designed to allow high school teachers to experience chemistry as it is actually practiced. A goal of the department is to help the teachers see themselves as chemists as well as teachers.
Courses and Requirements
The program normally consists of three summers of work; a fourth summer might be needed depending on the background of the individual teacher. Candidates must complete seven graduate credits, including research and thesis. A graduate class open only to M.A. candidates is offered each summer. Course work for graduate credit at Bucknell during the regular academic year can be counted toward the seven credits needed. Transfer of credit from other institutions may be accepted at the discretion of the department.
In addition to course work, each student will choose a research adviser before starting the first summer of work. The student will normally conduct research with that adviser for the duration of the program; the research will culminate in a written thesis. Students will present and orally defend a master’s thesis summarizing the results of their research.
Students must be full-time high school teachers. A letter of recommendation and support from the principal of the school is required. An undergraduate degree in chemistry is not required; if the degree is not in chemistry, a significant number of chemistry courses must have been completed.
Bucknell will provide free housing during the summer for all M.A. candidates. In addition, by applying to the Office of Finance, M.A. students who are teachers in service may obtain a substantial discount in tuition. Forms are available at the Graduate Studies Office. Research assistantships are awarded to M.A. students on the basis of availability of funds and on seniority in the program.
Graduate courses in Chemistry
604. X-ray Crystallography (I or II) Half to full course.
Independent study. Symmetry (point, plane, and space groups), diffraction (reciprocal space, precession photographs, automated data collection) and structural solution (Patterson Maps, Electron Density Maps, Refinement). Prerequisite: permission of the instructor.
613. Synthetic Organic Chemistry (I or II; 3, 0)
Modern synthetic organic chemistry, with examples involving complex natural products. Application of organic mechanism, synthetic strategy, and advanced transformations to total synthesis.
614. Mechanistic Organic Chemistry (I or II; 3, 0)
Thermal and kinetic aspects of organic reactions are discussed along with the effect of substituents, solvents, and stereochemistry on reaction pathways. Qualitative molecular orbit theory of organic compounds is covered in depth. Weekly problem sessions are held.
617. Special Topics in Organic Chemistry (I or II; R; 4, 0)
Available by independent study. Prerequisites: permission of the instructor.
622. Inorganic Chemistry II (II; 3, 4)
Survey course in modern inorganic chemistry covering transition metal, coordination, organometallic, and bioinorganic chemistry. Laboratory will consist of synthetic and physical measurements as well as the manipulation of air-sensitive materials..
627. Special Topics in Inorganic Chemistry (I or II; R; 4, 0)
Topics vary. Available by independent study.
632. Analytical Chemistry II (I; 3, 4)
Theory and practice of techniques of instrumental analysis including spectrophotometry, fluorescence, mass spectrometry, atomic absorption, chromatography, capillary electrophoresis, and dynamic electrochemistry.
637. Special Topics in Analytical Chemistry (I or II; 4, 0)
Available by independent study. Prerequisites: permission of the instructor.
640. Biological Physical Chemistry (II; 3, 4)
Introduction to physical chemistry for life science students, with emphasis on thermodynamics, hydrodynamics and spectroscopy.
641. Physical Chemistry I (I; 3, 4)
Introductory physical chemistry with emphasis on thermodynamics, kinetics, and electrochemistry.
642. Physical Chemistry II (II; 3, 4)
Introductory physical chemistry with emphasis on quantum mechanics, structure and bonding, molecular spectroscopy and statistical mechanics. The customized laboratory experience will emphasize applications of spectroscopy and computational methods. Prerequisite: CHEM 341.
643. Physical Chemistry for Engineers (I; 3, 1)
Introductory physical chemistry for engineers with emphasis on thermodynamics and electrochemistry.
647. Special Topics in Physical Chemistry (I or II; 4, 0)
Available by independent study. Prerequisites permission of the instructor.
651. Biochemistry I (I; 4, 0)
Introduction to biological chemistry with emphasis on the structure and function of proteins, lipids, carbohydrates and nucleic acids, kinetics and mechanisms of enzymes, bioenergetics, and metabolism.
652. Biochemistry II (II; 4, 0)
Advanced topics in protein structure and function, protein folding, enzyme mechanisms, electron transport and free-energy coupling mechanisms, biosynthesis, metabolic regulation, and supramolecular assemblies. Prerequisite: CHEM 351 or permission of the instructor.
657. Special Topics in Biochemistry (I or II; 3, 1)
Structure/function relationships and dynamics of biomolecules. Prerequisite: permission of the instructor.
658. Biochemical Methods (II; 2, 0)
A course in laboratory techniques including cell fractionation, protein, and nucleic acid analysis. Spectrophotometry, chromatography, centrifugation, electrophoresis, and mass spectrometry are emphasized. Prerequisites: permission of the instructor.
660. Advanced Environmental Chemistry (I; 4, 0)
Chemistry of the atmosphere, hydrosphere and lithosphere. Natural processes and anthropogenic effects will be discussed. Prerequisite: permission of the instructor.
675 and 676. Research (I and II; R; 0; 6-12) One-half to two course credits
685 and 686. Seminar (I and II; 3, 0) Half course
699. Thesis (I or II or S; 6) Half or full course
Courses for the M.A. Summer Chemistry Program for High School Teachers
610. Advanced Organic Chemistry for High School Teachers
620. Advanced Inorganic Chemistry for High School Teachers
630. Advanced Analytical Chemistry for High School Teachers
645. Advanced Physical Chemistry for High School Teachers
650. Advanced Biochemistry for High School Teachers
665. Advanced Environmental Chemistry for High School Teachers
677. Research Methods for High School Teachers